Palladium-Catalyzed Carboxylative Coupling of Allylstannanes and allyl halides

Russell J. Franks

Palladium-Catalyzed Carboxylative Coupling of Allylstannanes and allyl halides

Stephen F Austin State University

Producción científica: Article

Resumen

A three-component carboxylative coupling between allyl halides, allylstannanes, and CO2 to produce allyl esters is catalyzed by Pd and Pt phosphine complexes. Allyl chloride and allyltributylstannane are thus converted to propenyl butenoate in excellent yield. Cross coupling of two different allyl components produces a nearly statistical mixture of all four possible esters. Tentative mechanistic pathways for the catalytic reaction are proposed.

Idioma original	Undefined/Unknown
Publicación	Faculty Publications
Estado	Published - ene 1 2000

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abstract = "A three-component carboxylative coupling between allyl halides, allylstannanes, and CO2 to produce allyl esters is catalyzed by Pd and Pt phosphine complexes. Allyl chloride and allyltributylstannane are thus converted to propenyl butenoate in excellent yield. Cross coupling of two different allyl components produces a nearly statistical mixture of all four possible esters. Tentative mechanistic pathways for the catalytic reaction are proposed. ",

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T1 - Palladium-Catalyzed Carboxylative Coupling of Allylstannanes and allyl halides

AU - Franks, Russell J.

PY - 2000/1/1

Y1 - 2000/1/1

N2 - A three-component carboxylative coupling between allyl halides, allylstannanes, and CO2 to produce allyl esters is catalyzed by Pd and Pt phosphine complexes. Allyl chloride and allyltributylstannane are thus converted to propenyl butenoate in excellent yield. Cross coupling of two different allyl components produces a nearly statistical mixture of all four possible esters. Tentative mechanistic pathways for the catalytic reaction are proposed.

AB - A three-component carboxylative coupling between allyl halides, allylstannanes, and CO2 to produce allyl esters is catalyzed by Pd and Pt phosphine complexes. Allyl chloride and allyltributylstannane are thus converted to propenyl butenoate in excellent yield. Cross coupling of two different allyl components produces a nearly statistical mixture of all four possible esters. Tentative mechanistic pathways for the catalytic reaction are proposed.

M3 - Article

JO - Faculty Publications

JF - Faculty Publications

ER -